Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior.
نویسندگان
چکیده
The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC6HF4) and (T(p-OMe)PP)Ru(NO)(OC(=O)CF3) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 24 شماره
صفحات -
تاریخ انتشار 2013